著書・論文

Update 2015/04/15


2015-2019

Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation Polymerization: Highly Selective Synthesis of π-Conjugated Polymers with Diketopyrrolopyrrole Units
Masayuki Wakioka,* Rina Takahashi, Nobuko Ichihara, and Fumiyuki Ozawa*
Macromolecules 2017, 50(3), 927-934. (DOI: 10.1021/acs.macromol.6b02679)

A Square Planar Complex of Platinum(0)
Katsuhiko Takeuchi, Hiro-omi Taguchi, Ippei Tanigawa, Shota Tsujimoto, Tsukasa Matsuo, Hiromasa Tanaka, Kazunari Yoshizawa, and Fumiyuki Ozawa*
Angew. Chem. Int. Ed. 2016, 55(49), 15347-15350. (DOI: 10.1002/anie.201609515)
*This paper was highlighted in RSC Chemistry World “Chemists knock platinum complex flat” (by F. Gomollon-Bel, 15 November 2016)

PNP-Pincer Type Phosphaalkene Complexes of Late Transition Metals
Fumiyuki Ozawa* and Yumiko Nakajima*
Chem. Rec. (Special Issue: Challenges in Catalysis: From Theory to Experiment) 2016, 16(5), 2314-2323. (DOI: 10.1002/tcr.201600054)

Structural analysis of poly(3-hexylthiophene) prepared via direct heteroarylation polymerization
Jean-Remi Pouliot, Masayuki Wakioka, Fumiyuki Ozawa, Yuning Li, Mario Leclerc*
Macromol. Chem. Phys 2016, 217(13), 1493-1500. (DOI: 10.1002/macp.201600050)

Unsymmetrical PNP-Pincer Type Phosphaalkene Ligands Pro-tected by a Fused-Ring Bulky Eind Group: Synthesis and Ap-plications to Rh(I) and Ir(I) Complexes
Hiro-omi Taguchi, Daichi Sasaki, Katsuhiko Takeuchi, Shota Tsujimoto, Tsukasa Matsuo, Hiromasa Tanaka, Kazunari Yoshizawa, and Fumiyuki Ozawa*
Organometallics (Special Issue: Organometallics in Asia) 2016, 35(10), 1526-1533. (DOI: 10.1021/acs.organomet.6b00113)

Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation Polymerization: Effective Prevention of Structural Defects Using Diamines
Eisuke Iizuka, Masayuki Wakioka, and Fumiyuki Ozawa*
Macromolecules 2016, 49(9), 3310-3317. (DOI: 10.1021/acs.macromol.6b00441)
*This paper was highlighted in Synfacts, 2016, 12, 0683. (DOI: 10.1055/s-0035-1562334)

Reactions of [Cu(X)(BPEP-Ph)] (X = PF6, SbF6) with silyl compounds. Cooperative bond activation involving non-coordinating anions
Yumiko Nakajima,* Takahiro Tsuchimoto, Yung-Hung Chang, Katsuhiko Takeuchi, and Fumiyuki Ozawa*
Dalton Trans. 2016, 45(5), 2079-2084. (DOI: 10.1039/C5DT03166D)

Iridium(I) Complexes Bearing a Noninnocent PNP-Pincer Type Phosphaalkene Ligand: Catalytic Application to Base-Free N-Alkylation of Amines with Alcohols
Yung-Hung Chang, Ippei Tanigawa, Hiro-omi Taguchi, Katsuhiko Takeuchi, and Fumiyuki Ozawa*
Eur. J. Inorg. Chem. 2016(6), 754-760. (DOI: 10.1002/ejic.201500900)

朝倉化学体系16「有機遷移金属化学」
小澤文幸・西山久雄
朝倉書店, 2016.

Synthesis of Donor-Acceptor Polymers Containing Thiazolo[5,4-d]thiazole Units via Palladium-Catalyzed Direct Arylation Polymerization
Masayuki Wakioka,* Satoru Ishiki, and Fumiyuki Ozawa*
Macromolecules 2015, 48(22), 8382-8388. (DOI: 10.1021/acs.macromol.5b01822)

C-H Bond Cleavage of Acetonitrile by Iridium Complexes Bearing PNP-Pincer Type Phosphaalkene Ligands
Yung-Hung Chang, Katsuhiko Takeuchi, Masayuki Wakioka, and Fumiyuki Ozawa*
Organometallics 2015, 34(10), 1957-1962. (DOI: 10.1021/acs.organomet.5b00207)

Mixed-Ligand Approach to Palladium-Catalyzed Direct Arylation Polymerization: Synthesis of Donor-Acceptor Polymers with Dithienosilole (DTS) and Thienopyrroledione (TPD) Units
Eisuke Iizuka, Masayuki Wakioka, and Fumiyuki Ozawa*
Macromolecules 2015, 48(9), 2989-2993. (DOI: 10.1021/acs.macromol.5b00526)

Catalytic Synthesis of an Unsymmetrical PNP-Pincer Type Phosphaalkene Ligand
Hiro-omi Taguchi, Yung-Hung Chang, Katsuhiko Takeuchi, and Fumiyuki Ozawa*
Organometallics 2015, 34(8), 1589-1596. (DOI: 10.1021/acs.organomet.5b00195)

1,8-Disubstituted Xanthylidene-Based Remote Carbenes: Photolytic Generation and Isolation of Low-Coordinate Palladium(II) Complex
Shun Sugawara, Manabu Abe, Yoshihisa Fujiwara, Masayuki Wakioka, Fumiyuki Ozawa, and Yosuke Yamamoto*
Eur. J. Inorg. Chem. 2015, (3), 534-541.

Remarkable Ligand Effect of P(2-MeOC6H4)3 on Palladium-Catalyzed Direct Arylation
Masayuki Wakioka, Yuki Nakamura, Michelle Montgomery, and Fumiyuki Ozawa*
Organometallics 2015, 34(1), 198-205.

パラジウム触媒直接的アリール化重合:π共役系高分子の新簡便合成法
脇岡正幸・小澤文幸
化学 2015, 70(5), 64-65.


2010-2014

Disproportionation of Bis(phosphaethenyl)pyridine Iron(I) Bromide Induced by tBuNC
Ya-Fan Lin, Nobuko Ichihara, Yumiko Nakajima,* and Fumiyuki Ozawa*
Organometallics 2014, 33(22), 6700-6703.

Effects of PAr3 Ligands on Direct Arylation of Heteroarenes with Isolated [Pd(2,6-Me2C6H3)(μ-O2CMe)(PAr3)]4 Complexes
Masayuki Wakioka, Yuki Nakamura, Yoshihiro Hihara, Fumiyuki Ozawa,* and Shigeyoshi Sakaki
Organometallics 2014, 33(21), 6247-6252

Synthesis and Structures of Nickel Complexes with a PN-Chelate Phosphaalkene Ligand
Katsuhiko Takeuchi, Ataru Minami, Yumiko Nakajima,* and Fumiyuki Ozawa*
Organometallics 2014, 33(19), 5365-5370.

Reduction of an Fe(I) Mesityl Complex Induced by pi-Acid Ligands
Ya-Fan Lin, Yumiko Nakajima,* and Fumiyuki Ozawa*
Dalton Trans. 2014, 43(24), 9032-9037.

Mechanism of N-H Bond Cleavage of Aniline by a Dearomatized PNP-Pincer Type Phosphaalkene Complex of Iridium(I)
Yung-Hung Chang, Yumiko Nakajima, Hiromasa Tanaka, Kazunari Yoshizawa,* and Fumiyuki Ozawa*
Organometallics 2014, 33(3), 715-721.

A Highly Efficient Catalyst for the Synthesis of Alternating Copolymers with Thieno[3,4-c]pyrrole-4,6-dione Units via Direct Arylation Polymerization
Masayuki Wakioka, Nobuko Ichihara, Yutaro Kitano, and Fumiyuki Ozawa*
Macromolecules 2014, 47(2), 626-631.

脇岡正幸・小澤文幸
化学便覧 応用化学編 第7版 (分担執筆)
日本化学会編, 丸善出版, 2014.

Facile N-H Bond Cleavage of Ammonia by an Iridium Complex Bearing a Non-innocent PNP-Pincer Type Phosphaalkene Ligand
Yung-Hung Chang, Yumiko Nakajima, Hiromasa Tanaka, and Kazunari Yoshizawa,* and Fumiyuki Ozawa*
J. Am. Chem. Soc. 2013, 135(32), 11791-11794.

Factors Controlling the Reactivity of Heteroarenes in Direct Arylation with Arylpalladium Acetate Complexes
Masayuki Wakioka, Yuki Nakamura, Yoshihiro Hihara, Fumiyuki Ozawa,* and Shigeyoshi Sakaki
Organometallics 2013, 32(15), 4423-4430.

Synthesis, Structures, and Reactivity of Ruthenium Complexes with PNP-pincer Type Phosphaalkene Ligands
Yumiko Nakajima,* Yuki Okamoto, Yung-Hung Chang, and Fumiyuki Ozawa*
Organometallics 2013, 32(10), 2918-2925.

A Bis(phosphaethenyl)pyridine Complex of Iridium(I): Synthesis and Catalytic Application to N‐Alkylation of Amines with Alcohols
Yung-Hung Chang, Yumiko Nakajima, and Fumiyuki Ozawa*
Organometallics 2013, 32(7), 2210-2215.

Lewis Acid Chemistry of a Cationic [CCH] Subunit in a Bisdisphenoidal Eight-Atom Tetrairon-Tetracarbon Cluster
Masaaki Okazaki,* Wataru Taniwaki, Kazuki Miyagi, Masato Takano, Satoshi Kaneko, and Fumiyuki Ozawa*
Organometallics 2013, 32(6), 1951-1957.

A Highly Efficient Catalytic System for Polycondensation of 2,7-Dibromo-9,9-dioctylfluorene and 1,2,4,5-Tetrafluorobenzene via Direct Arylation
Masayuki Wakioka, Yutaro Kitano, and Fumiyuki Ozawa*
Macromolecules 2013, 46(2), 370-374.

パラジウム触媒直接的アリール化重合:π共役系高分子の新合成法
脇岡正幸・小澤文幸
OM News 2013, 66-71.

Direct Arylation of 2-Methylthiophene with Isolated [PdAr(μ-O2CR)(PPh3)]n Complexes: Kinetics and Mechanism
Masayuki Wakioka, Yuki Nakamura, Qifeng Wang, and Fumiyuki Ozawa*
Organometallics 2012, 31(13), 4810-4816.

Synthesis and Structure of Cubane-Type Tetrairon Clusters Possessing μ3-Isonitrile Ligands. Reductive Coupling of Two Isonitriles on Redox-Responsive Tetrairon Reaction Sites
Masaaki Okazaki,* Kosei Suto, Naotsugu Kudo, Masato Takano, and Fumiyuki Ozawa*
Organometallics 2012, 31(11), 4110-4113.

Synthesis of End-capped Regioregular Poly(3-hexylthiophene)s via Direct Arylation
Qifeng Wang, Masayuki Wakioka, and Fumiyuki Ozawa*
Macromol Rapid Commun. 2012, 33(14), 1203-1207.

Redox Chemistry of Bis(phosphaethenyl)pyridine Iron Complexes
Yumiko Nakajima,* and Fumiyuki Ozawa*
Organometallics 2012, 31(5), 2009-2015.

Reactions of Bromoacetylene with Primary Amine on a Butterfly-Type Tetrairon Core to Give Isonitrile and Methyne through Oxidation and Deprotonation
Masaaki Okazaki,* Takahiro Tsuchimoto, Yuki Nakazawa, Masato Takano, and Fumiyuki Ozawa*
Organometallics 2011, 30(13), 3487-3489.

Synthesis and Coordination Behavior of CuI Bis(phosphaethenyl)pyridine Complexes
Yumiko Nakajima,* Yu Shiraishi, Takahiro Tsuchimoto, and Fumiyuki Ozawa*
Chem. Commun. 2011, 47(22), 6332-6334.

Direct Arylation of Heteroarenes Catalyzed by a Pd/1,10-Phenanthroline Complex
Ryo Takita,* Daichi Fujita, and Fumiyuki Ozawa*
Synlett (Special Issue dedicated to Professors Lixin Dai and Xiyan Lu) 2011, (7), 959-963.

Enhanced Absorption and Fluorescence Efficiency of Silylethynyl-Functionalized Oligothiophenes and Thieno[3,2-b]thiophene
Kengo Asai, Gen-ichi Konishi,* Yumiko Nakajima, Susumu Kawauchi, Fumiyuki Ozawa, and Kazuhiko Mizuno
J. Organomet. Chem. (Special Issue: Frontiers in Organometallic Chemistry, 24th International Conference on Organometallic Chemistry ICOMC) 2011, 696(6), 1266-1271.

宮浦憲夫, 鈴木寛治, 小澤文幸, 山本陽介, 永島英夫 編
現代化学増刊 44「有機金属化学の最前線 −多様な元素を使いこなす−」
東京化学同人, 2011.

小澤文幸
触媒調製ハンドブック 第4編均一系触媒・第3章オレフィンメタセシス(ルテニウム触媒)
岩本正和監修, エヌ・ティー・エス, 2011.

Stereocontrolled Synthesis and Photoisomerization Behavior of All-cis and All-trans Poly(m-phenylenevinylene)s
Masayuki Wakioka, Masashi Ikegami, and Fumiyuki Ozawa*
Macromolecules 2010, 43(17), 6980-6985.

Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene)
Qifeng Wang, Ryo Takita,* Yuuta Kikuzaki, and Fumiyuki Ozawa*
J. Am. Chem. Soc. (communication) 2010, 132(33), 11420-11421.

Axially Chiral Anilido-Aldimine Aluminum Complexes with a Pseudobinaphthyl Skeleton
Kazuhiro Hayashi, Yumiko Nakajima, Fumiyuki Ozawa, and Takeo Kawabata*
Chem. Lett. 2010, 39, 643-645.

Electronic Structure of Four-coordinate Iron(I) Complex Supported by a Bis(phosphaethenyl)pyridine Ligand
Yumiko Nakajima,* Yoshihide Nakao, Shigeyoshi Sakaki, Yoshinori Tamada, Teruo Ono, and Fumiyuki Ozawa*
J. Am. Chem. Soc. (communication) 2010, 132(29), 9934-9936.

Substituent Effects on P-C Reductive Elimination from Styrylpalladium(II) Phosphine Complexes
Masayuki Wakioka, and Fumiyuki Ozawa*
Organometallics (The Dietmar Seyferth Festschrift) 2010, 29(21), 5570-5578.

Synthesis and Structures of Platinum Diphenylacetylene and Dithiolate Complexes bearing Diphosphinidenecyclobutene Ligands (DPCB-Y)
Yumiko Nakajima, Mitsuharu Nakatani, Kyohei Hayashi, Yu Shiraishi, Ryo Takita, Masaaki Okazaki, and Fumiyuki Ozawa*
New J. Chem. (Special Issue for Pacifichem 2010) 2010, 34(8), 1713-1722.


2005-2009

Redox-Active Phosphorus Ligands Bearing a [4Fe-4C] Core Substituent
Masaaki Okazaki,* Ken-ichi Yoshimura, Masato Takano, and Fumiyuki Ozawa*
Organometallics 2009, 28(24), 7055-7058.

The Effects of Primary Structures on Photo-induced Insolubilization of All-cis Poly(p-phenylenevinylene)s in Thin Films
Yuichiro Mutoh, Yasutaka Yamamoto, Masayuki Wakioka, Ryo Takita, Jun-ichi Nakamura, Toshiya Iida, and Fumiyuki Ozawa*
Bull. Chem. Soc. Jpn. 2009, 82(12), 1533-1537.

A Highly Selective Catalytic System for the Cross-Coupling of (E)-Styryl Bromide with Benzeneboronic Acid: Application to the Synthesis of All-trans Poly(arylenevinylene)s
Masayuki Wakioka, Yuichiro Mutoh, Ryo Takita, and Fumiyuki Ozawa*
Bull. Chem. Soc. Jpn. 2009, 82(10), 1292-1298 (Selected Paper).

The Mechanism of C-P Reductive Elimination from trans-[Pd(CH=CHPh)Br(PMePh2)2]
Masayuki Wakioka, Yumiko Nakajima, and Fumiyuki Ozawa*
Organometallics 2009, 28(8), 2527-2534.

Redox-responsive Recombination of Carbon-Carbon Bonds on Flexible Tetrairon Cores
Masaaki Okazaki,* Masato Takano, and Fumiyuki Ozawa*
J. Am. Chem. Soc. (communication) 2009, 131(5), 1684-1685.

Synthesis, Structures, and Reactions of Dirhodium Complexes Bearing 1,2-Diphenyl-3,4-diphosphinidenecyclobutene Ligand (DPCB)
Masaaki Okazaki,* Akito Hayashi, Ching-Feng Fu, Shiuh-Tzung Liu, and Fumiyuki Ozawa*
Organometallics 2009, 28(3), 902-908.

小澤文幸
ジホスフィニデンシクロブテン錯体の構造と触媒機能
有機合成化学協会誌 2009, 67(5), 529-539.

小澤文幸
触媒便覧 (分担執筆)
触媒学会編, 講談社, 2009.

Synthesis and Ligand Properties of 1-Phosphaethenyl-2-phosphanylferrocenes
Ryo Takita, Yuko Takada, Rader S. Jensen, Masaaki Okazaki, and Fumiyuki Ozawa*
Organometallics 2008, 27(23), 6279-6285.

Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes
Akito Hayashi, Takahiko Yoshitomi, Kazutoshi Umeda, Masaaki Okazaki, and Fumiyuki Ozawa*
Organometallics 2008, 27(10), 2321-2327.

Synthesis and Structures of Platinum(0) Alkyne Complexes with Extended π-Conjugated Systems
Kyohei Hayashi, Mitsuharu Nakatani, Akito Hayashi, Masato Takano, Masaaki Okazaki, Kozo Toyota, Masaaki Yoshifuji, and Fumiyuki Ozawa*
Organometallics 2008, 27(9), 1970-1972.

Reaction of trans-Pd(styryl)Br(PMePh2)2 with Styryl Bromide Affording 1,4-Diphenylbutadiene. An Unexpected Homocoupling Process Induced by P-C Reductive Elimination
Masayuki Wakioka, Masato Nagao, and Fumiyuki Ozawa*
Organometallics 2008, 27(4), 602-608.

脇岡正幸・滝田 良・小澤文幸
遷移金属触媒によるπ共役系高分子の構造制御合成
日本ゴム協会誌 2008, 81(10), 431-437.

Synthesis, Structures, and Catalytic Properties of Late-Transition-Metal 2,6-Bis(2-phosphaethenyl)pyridine Complexes
Akito Hayashi, Masaaki Okazaki, Fumiyuki Ozawa,* and Rika Tanaka
Organometallics 2007, 26(21), 5246-5249.

Photoisomerization Mechanism of All-Z-Oligo(phenylenevinylene)s
Masashi Ikegami, Masato Nagao, Hiroyuki Katayama, Fumiyuki Ozawa, and Tatsuo Arai*
Bull. Chem. Soc. Jpn. 2007, 80(9), 1833-1835.

Cationic Iridium(III) Complexes Bearing Phosphaalkene and 2-Pyridylphenyl Ligands
Akito Hayashi, Takeshi Ishiyama, Masaaki Okazaki, and Fumiyuki Ozawa*
Organometallics 2007, 26(15), 3708-3712.

Intra- and Intermolecular Hydroamination of Alkynes Catalyzed by ortho-Metalated Iridium Complexes
Rung-Yi Lai, K. Surekha, Akito Hayashi, Fumiyuki Ozawa, Yi-Hong Liu, Shie-Ming Peng, and Shiuh-Tzung Liu*
Organometallics 2007, 26(4), 1062-1068.

Synthesis and Catalytic Properties of Cationic Palladium(II) and Rhodium(I) Complexes Bearing Diphosphinidinecyclobutene Ligands
Rader S. Jensen, Kazutoshi Umeda, Masaaki Okazaki, Fumiyuki Ozawa,* and Masaaki Yoshifuji
J. Organomet. Chem. (Special Issue for Dynamic Complexes), 2007, 692(1-3), 286-294.

小澤文幸・片山博之
π共役系高分子の構造制御合成
高分子 2007, 56, 216-220.

Catalytic Applications of Transition Metal Complexes Bearing Diphosphinidenecyclobutenes (DPCB)
Fumiyuki Ozawa and Masaaki Yoshifuji
Dalton Trans. (Perspective) 2006, (42), 4987-4995.

Cyclodehydration of cis-2-Butene-1,4-diol with Active Methylene Compounds Catalyzed by a Diphosphinidenecyclobutene-coordinated Palladium Complex
Hiromi Murakami, Yukio Matsui, Fumiyuki Ozawa,* and Masaaki Yoshifuji
J. Organomet. Chem. (The Special Issue for 6th JOM Symposium) 2006, 691(14), 3151-3156.

Stereoselective Synthesis of cis- and trans-Oligo(phenylenevinylene)s via Palladium-Catalyzed Cross-Coupling Reactions
Hiroyuki Katayama,* Masato Nagao, Fumiyuki Ozawa,* Masashi Ikegami, and Tatsuo Arai
J. Org. Chem. 2006, 71(7), 2699-2705.

Thermal, Structural, and Viscoelastic Characterization of cis-Poly(phenylene vinylene) Related to its Photo-Isomerization
Hiroyuki Katayama, Fumiyuki Ozawa, Yumi Matsumiya, and Hiroshi Watanabe*
Polymer J. 2006, 38(2), 184-189.

Stereocontrolled Synthesis and Characterization of cis-Poly(arylenevinylene)s
Hiroyuki Katayama,* Masato Nagao, Tatsuro Nishimura, Yukio Matsui, Masayuki Wakioka, and Fumiyuki Ozawa*
Macromolecules 2006, 39(6), 2039-2048.

小澤文幸
ノーベル化学賞解説:高効率オレフィンメタセシス触媒 −有機合成に大革新をもたらした有機金属錯体−
化学 2006, 61, 12-14.

小澤文幸・野村琴広
ノーベル化学賞解説:高活性オレフィンメタセシス触媒の開発
科学 2006, 76, 18-20.

Highly (Z)-Selective Hydrosilylation of Terminal Alkynes Catalyzed by a Diphosphinidenecyclobutene-coordinated Ruthenium Complex: Application to the Synthesis of (Z,Z)-Bis(2-bromoethenyl)arenes
Masato Nagao, Kimihiro Asano, Kazutoshi Umeda, Hiroyuki Katayama, and Fumiyuki Ozawa*
J. Org. Chem. 2005, 70(25), 10511-10514.

Low-Coordinated Diphosphinidenecyclobutene Ligands: A New Entry for Palladium-Catalyzed Cyanation of Aryl Bromides
R. S. Jensen, A. S. Gajare, K. Toyota, M. Yoshifuji, and F. Ozawa
Tetrahedron Lett. 2005, 46(50), 8645-8647.

(Z)-Selective Cross-Dimerization of Arylacetylenes with Silylacetylenes Catalyzed by Vinylideneruthenium Complexes
Hiroyuki Katayama,* Hiroshi Yari, Masaki Tanaka, and Fumiyuki Ozawa*
Chem. Commun. 2005, (34), 4336-4338.

C-Si Reductive Elimination from cis-Vinyl(silyl)platinum(II) Complexes
Fumiyuki Ozawa,* Toshikazu Tani, and Hiroyuki Katayama
Organometallics 2005, 24(10), 2511-2515.

Insertion of Phenylacetylene into Pt(SnMe3)2(PMe2Ph)2
Takashi Sagawa, Kazutaka Ohtsuki, Takeshi Ishiyama, and Fumiyuki Ozawa*
Organometalics 2005, 24(7), 1470-1477.

Low-Coordinated Diphosphinidenecyclobutene Ligands: A New Entry for Stille Cross-Coupling of Aryl Bromides
Anil S. Gajare, R. S. Jensen, Kozo Toyota, Masaaki Yoshifuji,* and Fumiyuki Ozawa
Synlett 2005, 144-148.

Stereocontrolled Synthesis and Optical Properties of All-cis Poly(phenylene vinylene)s (PPVs): A Method for Direct Patterning of PPVs
Hiroyuki Katayama,* Masato Nagao, Tatsuro Nishimura, Yukio Matsui, Kazutoshi Umeda, Kensuke Akamatsu, Takaaki Tsuruoka, Hidemi Nawafune, and Fumiyuki Ozawa*
J. Am. Chem. Soc. 2005, 127(12), 4350-4353.

Synthesis and Property of BrCCH- and BrCCBr-Coordinated Tetrairon Clusters
Masaaki Okazaki,* Masato Takano, and Ken-ichi Yoshimura
J. Organomet. Chem. (The Special Issue for Young Scientists in Organometallic Chemistry 2005) 2005, 690(23), 5318-5332.

小澤文幸・片山博之・豊田耕三・吉藤正明
sp2 混成リン配位子をもつ特異な遷移金属錯体触媒
触媒 2005, 47, 544-549.

小澤文幸
現代化学増刊 43「最新有機合成化学」, 8. リン配位子の化学
奈良坂紘一・岩澤信治編、東京化学同人(2005); pp 107-122.

片山博之・小澤文幸
ルテニウム触媒によるオレフィンメタセシス重合
日本接着学会誌 2005, 41(1), 34-40.


2000-2004

Solvent Free Amination Reactions of Aryl Bromides at Room Temperature Catalyzed by a (π-Allyl)palladium Complex Bearing a Diphosphinidenecyclobutene Ligand
Anil S. Gajare, Kozo Toyota, Masaaki Yoshifuji,* and Fumiyuki Ozawa
J. Org. Chem. 2004, 69(19), 6504-6506.

Application of a diphosphinidenecyclobutene ligand in the solvent free copper-catalysed amination reactions of aryl halides
Anil S. Gajare, Kozo Toyota, Masaaki Yoshifuji,* and Fumiyuki Ozawa
Chem. Commun. 2004, (17), 1994-1995.

Vinylideneruthenium Complexes in Catalysis
Hiroyuki Katayama and Fumiyuki Ozawa
Coord. Chem. Rev. 2004, 248(15-16), 1703-1715.

Synthesis and Catalytic Properties of Diphosphinidenecyclobutene-coordinated Palladium and Platinum Complexes
Fumiyuki Ozawa and Masaaki Yoshifuji
C. R. Chimie 2004, 7(8-9), 747-754.

Insertion of Phenylacetylene into [Pt(GeMe3)(SnMe3)(PMe2Ph)2]
Takashi Sagawa, Rika Tanaka, and Fumiyuki Ozawa*
Bull. Chem. Soc. Jpn. 2004, 77(7), 1287-1295.(BCSJ Award)

Facile and Selective Deallylation of Allyl Ethers Using Diphosphinidenecyclobutene-coordinated Palladium Catalysts
Hiromi Murakami, Tatsuya Minami, and Fumiyuki Ozawa*
J. Org. Chem. 2004, 69(13), 4482-4486.

Catalytic C-O Bond Cleavage of Allylic Alcohols using Diphosphinidenecyclobutene-coordinated Palladium Complexes. A Mechanistic Study
Fumiyuki Ozawa,* Takeshi Ishiyama, Shogo Yamamoto, Seiji Kawagishi, Hiromi Murakami, and Masaaki Yoshifuji
Organometallics 2004, 23(8), 1698-1707.

Synthesis, Structures, and Reactions of Methylplatinum(II) and -palladium(II) Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB-Y)
Fumiyuki Ozawa,* Seiji Kawagishi, Takeshi Ishiyama, and Masaaki Yoshifuji
Organometallics 2004, 23(6), 1325-1332.

Polyaddition of 2,7-Diethynyl-9,9-dioctylfluorene Using Regio- and Stereoselective Alkyne Dimerization Catalysts
Hiroyuki Katayama,* Mari Nakayama, Tadashi Nakano, Chikaya Wada, Kensuke Akamatsu, and Fumiyuki Ozawa*
Macromolecules 2004, 37(1), 13-17.

小澤文幸
有機合成のための触媒反応103
檜山為次郎・野崎京子編、東京化学同人(2004); pp 64-67.

小澤文幸・南 達哉
第 5 版実験化学講座21 有機遷移金属化合物・超分子錯体
日本化学会編(2004); pp 308-327.

片山博之・小澤文幸
第 5 版実験化学講座18 金属を用いる有機合成
日本化学会編(2004); pp 311-327.

Alkyne-Insertion into cis-Silyl(stannyl)platinum(II) Complexes
Takashi Sagawa, Yasunobu Sakamoto, Rika Tanaka, Hiroyuki Katayama, and Fumiyuki Ozawa*
Organometallics 2003, 22(22), 4433-4445.

Ring-Opening Metathesis Polymerization Using Alkenyl Sulfides as Chain-Transfer Agents: Efficient Routes to Unsymmetrical Poly(norbornene)-Based Macroinitiators Bearing a Terminal Hydroxy Group
Hiroyuki Katayama,* Yosuke Fukuse, Yuko Nobuto, Kensuke Akamatsu, and Fumiyuki Ozawa*
Macromolecules 2003, 36(19), 7020-7026.

Preparation and C-Si Reductive Elimination Behavior of cis-Alkynyl(silyl)platinum(II) Complexes
Fumiyuki Ozawa* and Takuya Mori
Organometallics 2003, 22(17), 3593-3599.

Convenient Route to Fischer-type Carbene Ruthenium Complexes: Highly Selective Catalysts for Ring-Opening Cross-Metathesis of Norborbene Derivatives
Hiroyuki Katayama,* Masato Nagao, and Fumiyuki Ozawa*
Organometallics 2003, 22(3), 586-593.

Stereocontrolled Synthesis of (E)- and (Z)-Poly(p-phenylenevinylene)s via Ruthenium-Catalyzed Hydrosilylation of p-Diethynylbenzene
Hiroyuki Katayama,* Masato Nagao, Rie Moriguchi, and Fumiyuki Ozawa*
J. Organomet. Chem. 2003, 676(1-2), 49-54.

Covalent Bond-Mediated Network Fabrication of Carboxylic Anhydride-Protected Gold Nanoparticles
Kensuke Akamatsu,* Jun Hasegawa, Hidemi Nawafune,* Hiroyuki Katayama, and Fumiyuki Ozawa
Trans. Mater. Res. Soc. Jpn. 2003, 28(3), 927-930.

Fumiyuki Ozawa
Current Methods in Inorganic Chemistry, 3. Fundamentals of Molecular Catalysis
H. Kurosawa and A. Yamamoto (Eds.), Elsevier Science, Amsterdam, 2003; Chapter 9 Reductive Elimination

ルテニウム錯体触媒による開環メタセシス重合:反応制御の進歩
片山博之、小澤文幸
触媒年鑑(2003)

小澤文幸
有機金属反応剤ハンドブック
玉尾皓平編著、化学同人(2003); pp 183-189, 241-242.

小澤文幸
化学便覧応用化学編第 6 版
日本化学会編、丸善 (2003); 4.3.3 重合反応、4.3.4 不斉反応、4.6.3 錯体触媒

遷移金属触媒によるポリ(p-フェニレンエチニレン) の合成:最近の進歩
片山博之
OM News 2003, 58.

Synthesis and Reactions of cis-Silyl(boryl)platinum(II) Complexes
Takashi Sagawa, Yasuaki Asano, and Fumiyuki Ozawa*
Organometallics 2002, 21(26), 5879-5886.

(π-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene (DPCB) Ligands: Highly Active Catalysts for Direct Conversion of Allylic Alcohols
Fumiyuki Ozawa,* Hideyuki Okamoto, Seiji Kawagishi, Shogo Yamamoto, Tatsuya Minami, and Masaaki Yoshifuji
J. Am. Chem. Soc. 2002, 124(37), 10968-10969.

Effect of Substituents on the Formation of Vinylideneruthenium(II) Complexes. X-ray Structures of RuCl2{=C=C(Z)Ph}(dcpmp) (Z = H, SiMe3; dcpmp = C5H3N(CH2PCy2)2)
Hiroyuki Katayama,* Chikaya Wada, Ken Taniguchi, and Fumiyuki Ozawa*
Organometallics 2002, 21(15), 3285-3291.

Ruthenium-catalyzed Hydrosilylation of Terminal Alkynes: Stereodivergent Synthesis of (E)- and (Z)-Alkenylsilanes
Hiroyuki Katayama,* Ken Taniguchi, Masayuki Kobayashi, Takashi Sagawa, Tatsuya Minami, and Fumiyuki Ozawa*
J. Organomet. Chem. 2002, 645(1-2), 192-200.

Ring-Opening Metathesis Polymerization of Norbornene Using Vinylic Ethers as Chain-Transfer Agents: Highly Selective Synthesis of Monofunctional Macroinitiators for Atom Transfer Radical Polymerization
Hiroyuki Katayama,* Fumiko Yonezawa, Masato Nagao, and Fumiyuki Ozawa*
Macromolecules 2002, 35(3), 1133-1136.

Highly Reactive Intermediate-Functionalized Gold Clusters: Synthesis and Immobilization on Silica Supports through Amide-Forming Coupling
Kensuke Akamatsu,* Jun Hasegawa, Hidemi Nawafune,* Hiroyuki Katayama, and Fumiyuki Ozawa
J. Mater. Chem. 2002, 12(10), 2862-2865.

(π-Allyl)palladium Complexes bearing Diphosphinidenecyclobutene Ligands: A Highly Active Catalyst for Hydroamination of 1,3-Dienes
Tatsuya Minami, Hideyuki Okamoto, Shintaro Ikeda, Rika Tanaka, Fumiyuki Ozawa,* and Masaaki Yoshifuji
Angew. Chem. Int. Ed. 2001, 40(23), 4501-4502.

Dehydrogenative Silylation of Ketones Catalyzed by Diphosphinidenecyclobutene-coordinated Platinum(II) Complexes
Fumiyuki Ozawa,* Shogo Yamamoto, Seiji Kawagishi, Masatomi Hiraoka, Shintaro Ikeda, Tatsuya Minami, Shigekazu Ito, Masaaki Yoshifuji
Chem. Lett. 2001, (10), 972-973.

C-Si 結合形成 vs. C-H 結合形成
小澤文幸
ケイ素化学協会誌 2001, 14, 3-6.

オレフィンメタセシス触媒:最近の進歩
片山博之、小澤文幸
有機合成化学協会誌 2001, 59(1), 40-51.

Highly Selective Ring-Opening/Cross-Metathesis Reactions of Norbornene Derivatives using Selenocarbene Complexes as Catalysts
Hiroyuki Katayama, Hideto Urushima, Tsuneo Nishioka, Chikaya Wada, Masato Nagao, and Fumiyuki Ozawa*
Angew. Chem. Int. Ed. 2000, 39(24), 4513-4515 (Hot Papers).

Synthesis and Reactions of Palladium and Platinum Complexes bearing Diphosphinidenecyclobutene Ligands. A Thermally Stable Catalyst for Ethylene Polymerization
Shintaro Ikeda, Fumie Ohhata, Masaki Miyoshi, Rika Tanaka, Tatsuya Minami, and Fumiyuki Ozawa*
Angew. Chem. Int. Ed. 2000, 39(24), 4512-4513.

Hydrosilylation of 1,4-Bis(trimethylsilyl)-1-buten-3-ynes using Late Transition Metal Hydrides as Catalyst Precursors
Yooichiroh Maruyama, Keido Yoshiuchi, and Fumiyuki Ozawa*
J. Organomet. Chem. (A special issue for "Metal Hydrides") 2000, 609(1), 130-136.

Olefin-Metathesis Reactions using Vinylideneruthenium(II) Complexes as Catalyst Precursors
Hiroyuki Katayama, Hideto Urushima, Fumiyuki Ozawa*
J. Organomet. Chem. (A special issue for "Catalytic Metathesis of Organic Compounds") 2000, 606(1), 16-25.

Thermolysis Reactions of cis-PtR(SiPh3)(PMe2Ph)2 in Solution
Koh Hasebe, Jun Kamite, Takuya Mori, Hiroyuki Katayama, and Fumiyuki Ozawa*
Organometallics 2000, 19(10), 2022-2030.

Mechanisms of C-Si and C-H Bond Formation of the Reactions of Alkenylruthenium(II) Complexes with Hydrosilanes
Yooichiroh Maruyama, Kunihiro Yamamura, Takashi Sagawa, Hiroyuki Katayama, and Fumiyuki Ozawa*
Organometallics 2000, 19(7), 1308-1318.

Synthesis and Properties of (η3-1-Methylallyl)palladium(II) Formates as Models of Intermediates in the Palladium-Catalyzed Reductive Cleavage of Allylic Carboxylates and Carbonates with Formic Acid
Masato Oshima, Toshiaki Sakamoto, Yooichiroh Maruyama, Fumiyuki Ozawa,* Isao Shimizu, and Akio Yamamoto*
Bull. Chem. Soc. Jpn. 2000, 73(2), 453-464.

The Chemistry of Organo(silyl)platinum(II) Complexes Relevant to Catalysis
Fumiyuki Ozawa
J. Organomet. Chem. 2000, 611(1-2), 332-342.